bicyclic

Aim:To sythesize pentanoate and hexanoate of caged bicyclic phosphate.

目的 :合成笼双环磷酸的戊酸酸衍生物。

Aim To develop a concise method for the synthesis of bicyclic azasugar and thiosugar with novel scaffold.

目的发展一种简洁合成具有新型骨架的双环氮杂糖和硫杂糖的新方法。

Abstract： Aim: To sythesize pentanoate and hexanoate of caged bicyclic phosphate.

摘 要： 目的：合成笼双环磷酸的戊酸酸衍生物。

Results Two bicyclic azasugars and a thiosugar were produced from L-sorbose in several steps.

结果经几步反应成功地从L-山梨糖合成了三种双环氮杂糖和硫杂糖。

Methods:Chloroform being solvent,under bath heat,4 hydroxymethyl caged bicyclic phosphate acylated with pentanoyl chloride and hexanoyl chloride dividedly.

方法:用氯仿作溶剂,在浴温条件下,4羟甲基笼双环磷酸分别与戊酰氯、酰氯发生酰化反应。