bicyclic

Aim:To sythesize pentanoate and hexanoate of caged bicyclic phosphate.

目的 :合成笼双环磷酸酯的戊酸酯及己酸酯衍生物。

Aim To develop a concise method for the synthesis of bicyclic azasugar and thiosugar with novel scaffold.

目的发展一种简洁合成具有型骨架的双环氮杂糖和硫杂糖的法。

Abstract： Aim: To sythesize pentanoate and hexanoate of caged bicyclic phosphate.

摘 要： 目的：合成笼双环磷酸酯的戊酸酯及己酸酯衍生物。

Results Two bicyclic azasugars and a thiosugar were produced from L-sorbose in several steps.

结果经几步应成功地从L-山梨糖合成了三种双环氮杂糖和硫杂糖。

Methods:Chloroform being solvent,under bath heat,4 hydroxymethyl caged bicyclic phosphate acylated with pentanoyl chloride and hexanoyl chloride dividedly.

法:用氯仿作溶剂,在浴温条件下,4羟甲基笼双环磷酸酯分别与戊酰氯、己酰氯发生酰化应。